Investigating the effect of different liquid densities on the time taken to release 25 ml of alcohols Essay

* interrogation question* Does the change in crystalline densities at the akin temperature strickle the eon interpreted to exempt 25 ml of the inebriantic drink from a 50 ml buret?* Variables* Independent variable The fluidness niggardness / g ml-1.* Dependent variable The quantify interpreted to release 25 ml of the alcohol from a burette / s.* Controlled variables* The volume of alcohol in a burette / ml.* The temperature of the alcohols / oC.* The absence of unnecessary substances or ions.* The same burette for the entire experiment.* Prediction* The conviction interpreted to release 25 ml of the alcohol from a 50 ml burette is, stated by F. Weinberg (1984) 1, dependent on flow velocity and in particular ar very sensitive to small changes in the density difference amongst the two gass.* My prediction is, the higher(prenominal) the liquid density is, the more epoch filmn for 25 ml of the alcohol to be released from the burette. The conviction restitutionn to rel ease 25 ml of alcohol increases in order methyl alcohol, Ethanol, Propan-1-ol, Butan-1-ol and Octan-1-ol.* manner* Apparatus* 50 ml burette (Uncertainty 0.500 ml).* Retort stand.* 125 ml ethanol C2H5OH 95.0%.* 125 ml methanol CH3OH 99.5%.* 125 ml propan-1-ol CH3(CH2)2OH 98%.* 125 ml butan-1-ol CH3(CH2)3OH 99%.* 125 ml octan-1-ol CH3(CH2)7OH 94%.* Thermometer (Uncertainty 0.0500 oC).* 5 x funnels.* 50 ml conic flask.* Casio stop stop (Uncertainty 0.0100 seconds).* Distilled piss.* run a risk assessment* The procedure uses poisonous alcohols. Notably, suggested by Department of Chemistry imperial beard College London (2006) 2, less than 2 teaspoons (2 ml) of methanol net cause blindness, and 2 table spoons (30 ml) can cause death. This toxicity is mainly due to it beingness converted in the body to formic acid and formaldehyde, which first ack-ack gun the cells in the retina, then the other vital organs. Plus, propan-1-ol is used as a common solvent and cleaning agent in c hemistry science laboratoryoratories. Also, because it evaporates rapidly, IPA is astray used in astringents to cool the skin and constrict surface p atomic look 18nthood vessels.* Goggles and lab coat be on that pointfore needed to be worn throughout the experiment.* Procedures1. Close the beleaguer and run some distilled urine into the top of the burette, then swish the burette up and down to permit the water clean all the inner(a) of the burette. Open the tap, let the water drain out.2. Attach the burette to the retort stand and take premeditation that the burette is upright and stable.3. Close the tap and use the funnel to mystify 25 ml of ethanol into the burette.4. Remove the funnel, make for sure that in that respect is no air bubble inside the burette. Measure the temperature of ethanol by the thermometer.5. Put the conical flask under the burette, adjust the height of the burette so that the tip of the burette is just above the lip of the conical flask.6. Open the tap and immediately start the stop watch.7. Stop the watch when 25 ml of ethanol is fully released from the burette.8. Continue to open the tap and collect the lieed ethanol in the burette.9. Repeat smell 1 to 8 four more measure.10. Then change ethanol with methanol, propan-1-ol, butan-1-ol and octan-1-ol. Experiment step 1 9 with each alcohol.* Range and repeatings of experiment* There are 5 different ranges (The lowest value 0.789 g ml-1 & the highest value 0.826 g ml-1, Please refer to entropy Collection and Processing - Processed information).* The sign procedure is repeated 5 times and thus 25 results are recorded.* Control of variables* The volume of each alcohol type remains unceasing for every test at 25 ml. Different volumes of the alcohol sample may cause inaccuracies in terms of measuring the time taken to release. For instance, larger volume of the same alcohol sample certainly takes tenacious-lasting time to be released.* The temperature of each alcoh ol sample need to remain constant for every test at 20 oC (293 K). The analysis, written by Weirauch, D. A., Jr. (1998, December) 3, of the high-temperature sp acquireing kinetics for liquids affecting density shows that they can be modified with a constant shift factor. Therefore, higher temperature of the same alcohol sample may stamp down the time taken for the alcohol to be released.* The burettes and funnels are rinsed carefully with distilled water prior to the experiment to ensure that inside the burettes do not contain whatever unnecessary substances/ions. If present, they may move with the alcohols to form products which have different liquid density, as opposed to genuine liquid densities of the alcohols at 20 oC (293 K).* The same burette is used for every measurement. This is because burettes from the same manufacturer cannot be guaranteed to have the same radius of the tips (possessing comparatively small values). The use of different burettes can result differences in the time taken for the alcohol to be released.DATA COLLECTION AND PROCESSING* blunt data tableAlcoholsDependent& single-handedvariablesEthanolMethanolPropan-1-olButan-1-olOctan-1-ol pellucid density/ g ml-1at 20 oC (293 K) 40.7890.7910.8040.8100.8261st repetition age taken to release 25 ml of alcohol from a burette / seconds 0.010039.043.067.082.01122nd repetitionTime taken / seconds 0.010041.044.069.081.01153rd repetitionTime taken / seconds 0.010038.046.070.083.01114th repetitionTime taken / seconds 0.010039.042.071.080.0114fifth repetitionTime taken / seconds 0.010040.045.070.079.0110.Table 2.1 shows the self-contained raw data table.* Processed data* Calculating the misbegotten time taken to release 25 ml of alcohol from a burette* Mean time taken / s = (1st + 2nd + 3rd + 4th + 5th psychometric test data) 5.AlcoholsDependent& independentvariablesEthanolMethanolPropan-1-olButan-1-olOctan-1-ol smooth-spoken density / g ml-1 at 20 oC (293K).0.7890.7910.8040.8100.826T he meanspirited time taken to release 25 ml of alcohol from a burette / 0.0100 seconds39.444.069.481.0112Table 2.2 shows the touch on mean time takento release 25 ml of alcohol from a burette.* Presentation of processed dataGraph 2.1 shows the relationship between the liquid density and the mean time taken to release 25 ml of each alcohol from a burette.* Treatment of uncertainties* I try to read off carefully volume of the burette from the bottom of the meniscus with my shopping mall level at the meniscus in order to make sure that the volume of each alcohol sample used is yet 25 ml.CONCLUSION AND EVALUATION* Graph analysis* According to the presented graph of the mean time taken to release 25 ml of different alcohols, there is a very toughened positive correlation between the liquid density and the mean time taken to release 25 ml of alcohol from a burette as a very honorable line of best fit can be observed. (Please refer to Data Collection and Processing - Presentation of processed data - Image 2.1).* remainder* The results demonstrate that, the higher the liquid density is, the longer time taken for 25 ml of the alcohol to be released from the burette.* The conclusion totally agrees with my hypothesis.* paygrade of procedures* Strengths* Safety in the laboratory is highly maintained (by wearing goggles, lab coat and being careful with glass apparatus to avoid any poisonous alcohols that may splash).* Standard ranges and repetitions are met, a very impregnable positive correlation between the liquid density and the mean time taken to release 25 ml of alcohol from a burette is observed.* Quantitative investigation, with repeats strongly supporting each other, successfully proves that the expectations based on scientific knowledge are totally correct.* Weaknesses* Several inevitable uncertainties fade throughout the whole experiment which may account for inaccuracies in the collected data.* The concentrations of the alcohols vary from 94.0 % to 99 .5 %. The differences in concentration of each alcohol affect the dependableness of the data, since 25 ml of pure alcohols (or 5 alcohols with the same concentration) may take different time to be released from the burette.* Although there is a very strong positive correlation between the liquid density and the mean time taken to release 25 ml of alcohol from a burette, the independent variables (liquid density) do not increase constantly due to the limited number of available alcohols (Please refer to Data Collection and Processing - Presentation of processed data - Image 2.1).* The entire procedures, although are simple, take a long time to finish because of the 50 ml burette need to take at least 3 times to extend 5 alcohol samples (5 repetitions for each alcohol), 25 ml each. Overall there are 15 times to add 25 alcohol samples since I decide to suss out 5 different alcohols. The more time I need to add more alcohols into the burette, the more likely inaccuracies to occur.* I mproving the investigation* The procedures can be partially replaced by computer data logging suggested by Laurence Rogers (1995) 5 to veto uncertainties from human errors when stopping the watch. The experiment can be programmed to collect the data (Time taken for 25 ml of the alcohol to be released from the burette) automatically.* More alcohols with liquid densities within the ranges (The lowest value 0.789 g ml-1 & the highest value 0.826 g ml-1) can be tested to fill the 2 gaps between methanol and propan-1-ol, butan-1-ol and octan-1-ol in the presented graph. For instance, penta-1-ol has the liquid density of 0.815 g ml-1 at 20 oC (293 K) 6.* Pure alcohols should be bought in the same concentration to ensure the reliability of the collected data. Otherwise, diluting the alcohols to the same concentration can be less expensive, yet time consuming.* A larger burette, for instance, with measuring volume of 75 ml (only 2 times to add 5 alcohol samples, 25 ml each) will reduce the times need to pour more alcohols into the burette to 10. Not only this change in equipment may save time of experimenting, but in addition minimise the uncertainties.Bibliography1 Weinberg, F. (1984, December). Fluid flow from a low to a higher density liquid. Metallurgical and Materials Transactions B, 15(4), 681. Abstract retrieved March 8, 2009, from Springer Link. electronic network site http//www.springerlink.com/content/n84726w432072592/2 Department of Chemistry. (2006, August 25). Biological effects of Methanol and Larger Alcohols. In Ethanol. Retrieved March 8, 2009, from Imperial College London. Web sitehttp//www.ch.ic.ac.uk/rzepa/mim/environmental/html/ethanol_text.htm3 Weirauch, D. A., Jr. (1998, December). Predicting the spreading kinetics of high-temperature liquids on solid surfaces (Vol. 12). Alcoa practiced Center. Retrieved March 8, 2009. doi10.1557/JMR.1998.04784 Process Calculator. (2009). SG. In Liquid Density. Retrieved March 8, 2009, from al-Qaida Business Models Pvt Ltd. Web site http//www.processcalculator.com/Liquid_Density.aspx5 Rogers, L. (1995, May). Sensors and The Data-Logger. In Hardware and software. Retrieved March 9, 2009, from schooltime of Education, University of Leicester Web site http//www.le.ac.uk/se/lto/logging/test1.html6 Process Calculator. (2009). SG. In Liquid Density. Retrieved March 8, 2009, from Radix Business Models Pvt Ltd. Web site http//www.processcalculator.com/Liquid_Density.aspx